2 edition of Addition reactions involving stable silenes. Formation of: I. Siloxetanes II. Silaazetidines. found in the catalog.
Addition reactions involving stable silenes. Formation of: I. Siloxetanes II. Silaazetidines.
Wayne Joseph.* Chatterton
Written in English
|The Physical Object|
|Number of Pages||227|
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Upon photolysis with light of λ ≥ nm 9a-c showed Brook type 1,3-Si → O migration reactions under formation of the silenes 10a-c with exo- and endocyclic Si[dbnd]C double bonds. Request PDF | Neopentylsilenes: Laboratory Curiosities or Useful Building Blocks for the Synthesis of Silaheterocycles.
| The formation, reactivity, and cycloaddition behavior of neopentylsilenes. Besides the above addition reactions, insertion reactions into Si O bonds of alkoxysilanes, and cyclosiloxanes are characteristic of silenes. Download: Download full-size image (9). A feature of compounds with a Si C double bond is their ability to react via a 2+2 by: A variety of relatively stable silenes react with representative nonenolizable aldehydes and ketones to yield moderately stable 1,2-siloxetanes, some of which have been isolated as solids.
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